Assembly of a M4L4 "folded-cube" using a T-shaped, right-angled ligand.
نویسندگان
چکیده
A new bipyridine ligand based on a T-shaped 2,4,7-trisubstituted benzimidazole framework was synthesized with a 90° angle between the two nitrogen donors. When combined with convergent [Pt(dppp)](2+) corners, eight right angles (four metal and four ligand) combine to form a M4L4 cluster with an unusual folded-cube structure.
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عنوان ژورنال:
- Dalton transactions
دوره 44 3 شماره
صفحات -
تاریخ انتشار 2015